Surface chemistry of room-temperature ionic liquids

被引:133
作者
Aliaga, Cesar [1 ]
Santos, Cherry S. [1 ]
Baldelli, Steven [1 ]
机构
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
关键词
D O I
10.1039/b703574h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In many applications of room-temperature ionic liquids, it has been recognized that the interface is a vital component. In electrochemistry, for instance, the electron transfer is significant to the efficiency of the solar cell and is very much dependent on the behavior of a given interface. This review presents the current state of knowledge of room-temperature ionic liquids in contact with solids, liquids, and gas phases. Experimental and molecular modeling studies have been conducted to investigate the surface structure and composition of ions in pure ionic liquids. However, surface studies on these liquids are still in its infancy and as the range of the available surface techniques and systematic investigations are increased, our understanding will improve which will lead to advances on this field.
引用
收藏
页码:3683 / 3700
页数:18
相关论文
共 137 条
[1]   Model for the conductivity of ionic liquids based on an infinite dilution of holes [J].
Abbott, AP .
CHEMPHYSCHEM, 2005, 6 (12) :2502-2505
[2]   Application of hole theory to the viscosity of ionic and molecular liquids [J].
Abbott, AP .
CHEMPHYSCHEM, 2004, 5 (08) :1242-1246
[3]   Design of improved deep eutectic solvents using hole theory [J].
Abbott, AR ;
Capper, G ;
Gray, S .
CHEMPHYSCHEM, 2006, 7 (04) :803-806
[4]  
Adamson A.W., 1967, Physical chemistry of surfaces
[5]   Sum frequency generation spectroscopy and double-layer capacitance studies of the 1-butyl-3-methylimidazolium dicyanamide-platinum interface [J].
Aliaga, Cesar ;
Baldelli, Steven .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (37) :18481-18491
[6]  
Anthony J. L., 2004, International Journal of Environmental Technology and Management, V4, P105
[7]  
Aroca R., 2006, Surface-Enhanced Vibrational Spectroscopy
[8]   INFRARED SPECTROELECTROCHEMISTRY [J].
ASHLEY, K ;
PONS, S .
CHEMICAL REVIEWS, 1988, 88 (04) :673-695
[9]   Potential-dependent reorientation of water molecules at an electrode/electrolyte interface studied by surface-enhanced infrared absorption spectroscopy [J].
Ataka, K ;
Yotsuyanagi, T ;
Osawa, M .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (25) :10664-10672
[10]   The effect of the anion on the physical properties of trihalide-based N,N-dialkylimidazolium ionic liquids [J].
Bagno, A ;
Butts, C ;
Chiappe, C ;
D'Amico, F ;
Lord, JCD ;
Pieraccini, D ;
Rastrelli, F .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (09) :1624-1630