AlInAs/InGaAs metal-semiconductor-metal (MSM) photodetectors with a low dark current density are fabricated using a surface modification process with phosphine (PH3) plasma. Phosphidization of the AlInAs cap layer reduces the surface state density and allows formation of high Schottky barrier with a tunnel metal-insulator-semiconductor (MIS) structure. A dark current density as low as 0.021 pA/mu m(2) at 10 V is obtained.