A novel approach to the construction of medium-ring carbocycles utilising the rearrangement of oxonium ylides generated from metal carbenoids

被引：24

作者：

Clark, JS

Bate, AL

Grinter, T

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] SmithKline Beecham Pharmaceut, Tonbridge TN11 9AN, Kent, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b100292i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Medium-ring carbocycles have been prepared by intramolecular reactions of metal carbenoids with tethered alpha -vinyl methyl ethers and subsequent [2,3] rearrangement of the presumed cyclic oxonium ylide intermediates.

引用

页码：459 / 460

页数：2

共 29 条

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