Deposition of PTFE thin films by ion beam sputtering and a study of the ion bombardment effect

被引:46
作者
He, JL [1 ]
Li, WZ [1 ]
Wang, LD [1 ]
Wang, J [1 ]
Li, HD [1 ]
机构
[1] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
ion beam assisted deposition; ion beam sputtering; polymer; ion beam bombardment; PTFE;
D O I
10.1016/S0168-583X(97)00630-7
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Ion beam sputtering technique was employed to prepare thin films of Polytetrafluroethylene (PTFE). Simultaneous ion beam bombardment during film growth was also conducted in order to study the bombardment effects. Infrared absorption (IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) analysis was used to evaluate the material's integrity. It was found that PTFE thin films could be grown at room temperature by direct sputtering of a PTFE target. The film's composition and structure were shown to be dependent on the sputtering energy. Films deposited by single sputtering at higher energy (similar to 1500 eV) were structurally quite similar to the original PTFE material. Simultaneous ion beam bombarding during film growth caused defluorination and structural changes. Mechanism for sputtering deposition of such a polymeric material is also discussed. (C) 1998 Published by Elsevier Science B.V.
引用
收藏
页码:512 / 516
页数:5
相关论文
共 11 条
[1]  
Beamsom G., 1992, HIGH RESOLUTION XPS
[2]  
CLARK DT, 1978, HDB XRAY PHOTOELECTR
[3]   POLYMER FILM FORMATION IN C2F6-H2 DISCHARGES [J].
DAGOSTINO, R ;
CRAMAROSSA, F ;
FRACASSI, F ;
DESIMONI, E ;
SABBATINI, L ;
ZAMBONIN, PG ;
CAPORICCIO, G .
THIN SOLID FILMS, 1986, 143 (02) :163-175
[4]   PLASMA POLYMERIZATION OF ETHYLENE AND THE SERIES OF FLUOROETHYLENES - PLASMA EFFLUENT MASS-SPECTROMETRY AND ESCA STUDIES [J].
DILKS, A ;
KAY, E .
MACROMOLECULES, 1981, 14 (03) :855-862
[5]  
DILKS A, 1981, ELECT SPECTROSCOPY
[6]  
HETZLER EK, 1983, J APPL PHYS, V49, P5617
[7]   Thin polymer films prepared by radio frequency plasma sputtering of polytetrafluoroethylene and polyetherimide targets [J].
Hishmeh, GA ;
Barr, TL ;
Sklyarov, A ;
Hardcastle, S .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1996, 14 (03) :1330-1338
[8]   RADIO-FREQUENCY SPUTTERING PROCESS OF A POLYTETRAFLUOROETHYLENE TARGET AND CHARACTERIZATION OF FLUOROCARBON POLYMER-FILMS [J].
MARECHAL, N ;
PAULEAU, Y .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (03) :477-483
[9]   ION-BEAM SPUTTERING DEPOSITION OF FLUOROPOLYMER THIN-FILMS [J].
QUARANTA, F ;
VALENTINI, A ;
FAVIA, P ;
LAMENDOLA, R ;
DAGOSTINO, R .
APPLIED PHYSICS LETTERS, 1993, 63 (01) :10-11
[10]  
TIKHOMIROV LA, 1983, HIGH ENERG CHEM+, V17, P267