A first example of macromolecular Ti(IV) Lewis acid in the catalytic enantioselective Mukaiyama reaction

被引：26

作者：

Mandoli, A ^{[1
]}

Pini, D ^{[1
]}

Orlandi, S ^{[1
]}

Mazzini, F ^{[1
]}

Salvadori, P ^{[1
]}

机构：

[1] CNR, Ctr Studio, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 09期

关键词：

D O I：

10.1016/S0957-4166(98)00127-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of a soluble copolymer P1 between styrene, divinylbenzene (DVB) and the enantiomerically pure salicylaldimine ligand 3c is described. The Lewis acid prepared from this macromolecular chiral ligand and Ti((OPr)-Pr-i)(4) has been used in the catalytic Mukaiyama reaction to afford benzyl (R)-3-hydroxy-3-phenylpropanoate 7. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1479 / 1482

页数：4

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