New polymeric structure of rhenium octahedral chalcocyanide complex:: Ln3+-derived network with one-dimensional channels

被引：38

作者：

Artemkina, SB

Naumov, NG

Virovets, AV

Gromilov, SA

Fenske, D

Fedorov, VE

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

rhenium; octahedral cluster; lanthanide; cyano-bridged complexes; polymeric structure;

D O I：

10.1016/S1387-7003(01)00230-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel cyanobridged coordination polymeric complex with octahedral rhenium cyanocluster anion [Re-6(mu (3) - Se)(8)(CN)(6)](4-) and Nd3+ cation has been synthesised and structurally characterised. Its solid-state structure contains a channel-type polymeric network built from cluster anions and Nd3+ through Re-CN-Nd-NC-Re interactions. For compound (H3O) {Nd(DMF)(3)(H2O)(3)} [Re6Se8(CN)(6)]. space group R3c, unit cell parameters are: a = 32.514(5): c = 25.255(5) Angstrom. V = 23122(7) Angstrom (3), R-f = 0.0762. A pair of isomorphic complexes has been obtained with Ln = Pr3+, Ho3+ (C) 2001 Published by Elsevier Science B.V.

引用

收藏

页码：423 / 426

页数：4

相关论文

共 22 条

[1] Cyano-bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) framework materials:: Versatile solid chemical sensors [J].

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) :2763-2772

[2] Cyano-bridged Re6Q8 (Q = S, Se) cluster-metal framework solids:: A new class of porous materials [J].

Beauvais, LG ;

Shores, MP ;

Long, JR .

CHEMISTRY OF MATERIALS, 1998, 10 (12) :3783-+

[3] STRUCTURE OF LACR(CN)65H2O [J].

DOMMANN, A ;

VETSCH, H ;

HULLIGER, F .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1994-1996

[4] STRUCTURE OF ERFE(CN)64H2O [J].

DOMMANN, A ;

VETSCH, H ;

HULLIGER, F ;

PETTER, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1992-1994

[5] Aqua(hexacyanoferrato-N)bis(mu-glycine)-glycinecerium(III) monohydrate [J].

GarciaGranda, S ;

Morales, AD ;

Ruiz, ER ;

Bertran, JF .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1679-1681

[6] CRYSTAL-STRUCTURE OF EUROPIUM TETRACYANOPALLADATE(II) 12-HYDRATE, EU2(PD(CN)4)3(H2O)12 [J].

KLEMENT, U .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 208 :288-290

[7] Heterometallic one-dimensional arrays containing cyanide-bridged lanthanide(III) and transition metals [J].

Knoeppel, DW ;

Liu, JP ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 1998, 37 (19) :4828-4837

[8] Unusual one-dimensional ladder structures containing divalent europium and the tetracyanometalates Ni(CN)(4)(2-) and Pt(CN)(4)(2-) [J].

Knoeppel, DW ;

Shore, SG .

INORGANIC CHEMISTRY, 1996, 35 (18) :5328-5334

[9] An unusual cyanide bridging lanthanide transition metal complex that contains the one-dimensional cationic array {[(DMF)16Yb6(μ6-O)(μ3-OH)8(μ-NC)Pd(μ-CN)(CN)2]6+}∞ [J].

Liu, JP ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 1998, 37 (21) :5410-+

[10] A solid-state route to molecular clusters: Access to the solution chemistry of [Re(6)Q(8)](2+) (Q=S, Se) core-containing clusters via dimensional reduction [J].

Long, JR ;

McCarty, LS ;

Holm, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (19) :4603-4616