Synthesis and thermal modulation of the fluorescence of a pyrene-arylmaleimide dyad and its Diels-Alder adduct

被引:16
作者
Wang, Z
Zhang, DQ [1 ]
Zhu, D
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.tetlet.2005.04.135
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The fluorescence of a pyrene-arylmaleimide dyad and its Diels-Alder adduct can be thermally modulated through reversible Diels-Alder reaction of arylmaleimide unit with furan. Moreover, the fluorescence intensities of the Diels-Alder adduct of dyad 1 with furan vary linearly with the temperatures of the corresponding solutions, demonstrating that these molecules are interesting compounds for Studies of fluorescent molecular thermometers. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4609 / 4612
页数:4
相关论文
共 27 条
[11]   SURFACE THERMOMETRY BY LASER-INDUCED FLUORESCENCE [J].
GOSS, LP ;
SMITH, AA ;
POST, ME .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1989, 60 (12) :3702-3706
[12]   Application of the Diels-Alder reaction to polymers bearing furan moieties. 2. Diels-Alder and retro-Diels-Alder reactions involving furan rings in some styrene copolymers [J].
Gousse, C ;
Gandini, A ;
Hodge, P .
MACROMOLECULES, 1998, 31 (02) :314-321
[13]   A novel lattice-hardening process to achieve highly efficient and thermally stable nonlinear optical polymers [J].
Haller, M ;
Luo, JD ;
Li, HX ;
Kim, TD ;
Liao, Y ;
Robinson, BH ;
Dalton, LR ;
Jen, AKY .
MACROMOLECULES, 2004, 37 (03) :688-690
[14]   REMOTE THERMAL IMAGING WITH 0.7-MU-M SPATIAL-RESOLUTION USING TEMPERATURE-DEPENDENT FLUORESCENT THIN-FILMS [J].
KOLODNER, P ;
TYSON, JA .
APPLIED PHYSICS LETTERS, 1983, 42 (01) :117-119
[15]   NON-CONTACT SURFACE-TEMPERATURE MEASUREMENT DURING REACTIVE-ION ETCHING USING FLUORESCENT POLYMER-FILMS [J].
KOLODNER, P ;
KATZIR, A ;
HARTSOUGH, N .
APPLIED PHYSICS LETTERS, 1983, 42 (08) :749-751
[16]   The application of the Diels-Alder reaction to polymers bearing furan moieties .1. Reactions with maleimides [J].
Laita, H ;
Boufi, S ;
Gandini, A .
EUROPEAN POLYMER JOURNAL, 1997, 33 (08) :1203-1211
[17]  
Liu Y., 1991, CHIN J PHARM, V22, P8
[18]   Fluorescent probes for monitoring temperature in organic solvents [J].
Lou, JF ;
Hatton, TA ;
Laibinis, PE .
ANALYTICAL CHEMISTRY, 1997, 69 (06) :1262-1264
[19]   Highly efficient and thermally stable electro-optic polymer from a smartly controlled crosslinking process [J].
Luo, JD ;
Haller, M ;
Li, HX ;
Kim, TD ;
Jen, AKY .
ADVANCED MATERIALS, 2003, 15 (19) :1635-+
[20]   Thermally responsive dendrons and dendrimers based on reversible furan-maleimide Diels-Alder adducts [J].
McElhanon, JR ;
Wheeler, DR .
ORGANIC LETTERS, 2001, 3 (17) :2681-2683