1,2-alkyl migration as a key element in the invention of cascade reactions catalyzed by π-acids

被引：182

作者：

Crone, Benedikt ^{[1
]}

Kirsch, Stefan F. ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 12期

关键词：

cascade reactions; catalysis; gold; platinum; rearrangement;

D O I：

10.1002/chem.200701985

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This brief overview highlights recent progress in the field of cascade reactions that are initiated by the activation of a pi-system using platinum and gold catalysts and that are coupled with a 1,2-alkyl migration step. While the reactions discussed aim to rapidly evolve molecular complexity, they are experimentally straightforward and easy to perform. Primarily guided by the type of 1,2-alkyl migration, methods are categorized as shifts to metal carbenoid centers and pinacol-type rearrangements.

引用

页码：3514 / 3522

页数：9

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