[ButNHP(μ-NBut)2PNH2], a novel building block for neutral and anionic polycyclic main group arrangements

被引:21
作者
Beswick, MA [1 ]
Elvidge, BR [1 ]
Feeder, N [1 ]
Kidd, SJ [1 ]
Wright, DS [1 ]
机构
[1] Univ Cambridge, Cambridge CB2 1EW, England
关键词
D O I
10.1039/b009000j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel precursor [(BuNHP)-N-t(mu -NBut)(2)PNH2] (1) provides easy access to polycyclic main group systems; reaction with Sb(NMe2)(3) gives the tricyclic species {[(BuNHP)-N-t(mu -NBut)(2)- P}(2){Me2NSb(mu -N)}(2)] (2), whereas reaction with an excess of (BuLi)-Li-n results in elimination of LiNH2 and the formation of the co-complex [{(BuNP)-N-t(mu -NBut)(2)P}(2)N]Li-3 ((BuLi)-Li-n)(2), (3), containing the unprecedented [{(BuNP)-N-t(mu -NBut)(2)P}(2)N](3-) trianion.
引用
收藏
页码:379 / 380
页数:2
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