Mo-Au combo catalysis for rapid 1,3-rearrangement of propargyl alcohols into α,β-unsaturated carbonyl compounds

被引：126

作者：

Egi, Masahiro ^{[1
]}

Yamaguchi, Yoshiko ^{[1
]}

Fujiwara, Noboru ^{[1
]}

Akai, Shuji ^{[1
]}

机构：

[1] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 09期

关键词：

D O I：

10.1021/ol800596c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of Mo and cationic Au catalysts dramatically accelerated the rearrangement of diverse propargyl alcohols, which includes a short reaction time, mild conditions, and high product yields. A practical application to the highly challenging primary propargyl alcohols and the N-alkynyl amides is achieved.

引用

页码：1867 / 1870

页数：4

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