Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines

被引：192

作者：

Matsuda, Naoki ^{[1
]}

Hirano, Koji ^{[1
]}

Satoh, Tetsuya ^{[1
]}

Miura, Masahiro ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 11期

关键词：

C-H BONDS; INTERMOLECULAR DIRECT ARYLATION; DIRECT ALKYNYLATION; CARBON-HYDROGEN; DERIVATIVES; AMIDATION; FUNCTIONALIZATION; 1,3,4-OXADIAZOLES; ACTIVATION; AZOLES;

D O I：

10.1021/ol200855t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The C-H amination of electron-deficient arenes such as polyfluoroarenes and azole compounds with O-acylated hydroxylamines effectively proceeds in the presence of a copper catalyst even at room temperature to provide the corresponding anilines and aminoazoles in good yields.

引用

页码：2860 / 2863

页数：4

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