A self-assembled spin cage

被引：60

作者：

Nakabayashi, Koji ^{[1
,2
]}

Ozaki, Yusuke ^{[1
,2
]}

Kawano, Masaki ^{[1
,2
]}

Fujita, Makoto ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Agcy, CREST, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 11期

关键词：

host-guest systems; molecular recognition; palladium; radicals; self-assembly;

D O I：

10.1002/anie.200704924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Going for a spin: The quantitative self-assembly of a verdazyl radical-cored ligand with [Pd(bpy)(NO3)2] (bpy = 2,2′-bipyridyl) generates a large M6L4 spin cage in which multiple spin centers effectively surround the cavity. The inclusion of a radical guest within the cavity induces spin-spin interactions between the host and the guest. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：2046 / 2048

页数：3

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