Kinetic resolution of racemic alkoxy oxiranes by chiral lithium amides

被引：17

作者：

Bigi, A

Mordini, A

Thurner, A

Faigl, F

Poli, G

Toke, L

机构：

[1] Dipartimento Chim Organ U Schiff, Ctr CNR Composti Eterocicl, I-50121 Florence, Italy

[2] Tech Univ Budapest, Hungarian Acad Sci, Res Grp, Dept Organ Chem Technol, H-1521 Budapest, Hungary

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 13期

基金：

新加坡国家研究基金会; 匈牙利科学研究基金会;

关键词：

D O I：

10.1016/S0957-4166(98)00239-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isomerization of alkoxy oxiranes with chiral lithium amides has been carefully investigated with the aim of finding an enantioselective approach to hydroxy enolethers, a class of compounds which can be used for further synthetic elaborations. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2293 / 2299

页数：7

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[21] A REGIOCONTROLLED AND STEREOCONTROLLED ACCESS TO 2,4-DIENOLS BY AMIDE/ALCOHOLATE-PROMOTED RING-OPENING OF DIHYDRO-PYRANS [J].