Mild and convenient one pot synthesis of N-hydroxyimides from N-unsubstituted imides

被引：25

作者：

Einhorn, C ^{[1
]}

Einhorn, J ^{[1
]}

Marcadal-Abbadi, C ^{[1
]}

机构：

[1] Univ Grenoble 1, CNRS, LEDSS UMR 5616, Lab Chim Biomimet, F-38041 Grenoble, France

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 05期

关键词：

D O I：

10.1081/SCC-100103264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new, one pot synthesis of various N-hydroxyimides from N-unsubstituted imides is described. Imides are first transformed into their N-Boc derivatives, which are next reacted with aqueous hydroxylamine, providing crystalline hydroxylammonium salts of the corresponding N-hydroxyimides. Filtration and acidic workup affords pure N-hydroxyimides.

引用

页码：741 / 748

页数：8

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