Synthesis of functionalized pyrroles via Gold(I)-catalyzed aza-claisen-type rearrangement

被引：141

作者：

Istrate, Florin M. ^{[1
]}

Gagosz, Fabien ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7652, Lab Synth Organ, F-91128 Palaiseau, France

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 16期

关键词：

D O I：

10.1021/ol0713032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Gold(I)-catalyzed cyclization of pentenynyl allyl tosylamides allows the rapid construction of functionalized pyrroles. The concerted aza-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.

引用

页码：3181 / 3184

页数：4

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