Simultaneous reverse and normal initiation in atom transfer radical polymerization

被引：192

作者：

Gromada, J ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 22期

关键词：

D O I：

10.1021/ma010864k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Atom transfer radical polymerization (ATRP) with concurrent reverse and normal initiation process was investigated. Bulk polymerizations of both n-butyl acrylate (BA) and styrene (St) were conducted using CuBr2 complexed with 1 equiv of tris(2-(dimethylamino)ethyl)amine (Me-6-TREN) as the catalytic system, initiated by 2,2'-azobis(isobutyronitrile) (AIBN) and an alkyl halide (RX). Polymerization of BA at 60 or 90 degreesC provided well-defined polymers with molecular weights up to 40 000 g/mol and low polydispersities (M-w/M-n < 1.10). Similar results were obtained for the polymerization of styrene at 110 degreesC. The effects of polymerization temperature and solubility were studied in order to moderate the high activity of the catalyst and the poor solubility of the Cu(Il) complex in monomers. Additionally, other parameters influencing this ATRP process are discussed.

引用

页码：7664 / 7671

页数：8

共 48 条

[31] Living/controlled radical polymerization of methyl methacrylate by reverse ATRP with DCDPS/FeCl3/PPh3 initiating system [J].

Qin, DQ ;

Qin, SH ;

Chen, XP ;

Qiu, KY .

POLYMER, 2000, 41 (20) :7347-7353

[32]

Qin DQ, 2000, J POLYM SCI POL CHEM, V38, P101, DOI 10.1002/(SICI)1099-0518(20000101)38:1<101::AID-POLA13>3.0.CO

[33]

2-3

[34] Emulsion polymerization of n-butyl methacrylate by reverse atom transfer radical polymerization [J].

Qiu, J ;

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 1999, 32 (09) :2872-2875

[35] Mechanistic aspect of reverse atom transfer radical polymerization of n-butyl methacrylate in aqueous dispersed system [J].

Qiu, J ;

Pintauer, T ;

Gaynor, SG ;

Matyjaszewski, K ;

Charleux, B ;

Vairon, JP .

MACROMOLECULES, 2000, 33 (20) :7310-7320

[36]

Qiu J, 2000, MACROMOL CHEM PHYSIC, V201, P1625, DOI 10.1002/1521-3935(20000901)201:14<1625::AID-MACP1625>3.0.CO

[37]

2-9

[38] Optimization of atom transfer radical polymerization using Cu(I)/tris(2-(dimethylamino)ethyl)amine as a catalyst [J].

Queffelec, J ;

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 2000, 33 (23) :8629-8639

[39] Halide anions as ligands in iron-mediated atom transfer radical polymerization [J].

Teodorescu, M ;

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 2000, 33 (07) :2335-2339

[40] Nickel-mediated living radical polymerization of methyl methacrylate [J].

Uegaki, H ;

Kotani, Y ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1997, 30 (08) :2249-2253

← 1 2 3 4 5 →