Anode materials for lithium ion batteries in the Li-Zn-P system

被引：25

作者：

Bichat, MP ^{[1
]}

Monconduit, L ^{[1
]}

Pascal, JL ^{[1
]}

Favier, F ^{[1
]}

机构：

[1] Univ Montpellier 2, CNRS, UMR 5072, Lab Agregats Mol & Mat Inorgan, F-34095 Montpellier, France

来源：

IONICS | 2005年 / 11卷 / 1-2期

关键词：

D O I：

10.1007/BF02430403

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper presents an exhaustive study of the Li-Zn-P system through the synthesis and electrochemical characterisation of several binary and ternary phases: Lig(9)ZnP(4), LiZnP, Zn3P2 (alpha and beta), ZnP2 (alpha and beta), LiZn, and LiZn4. Three synthetic routes have been used to prepare these materials: ceramic synthesis and ball milling without and with annealing. Li-Zn-P system phases have been evaluated through X-ray diffraction and electrochemical reactivity towards lithium. Exhibiting high specific capacities at potentials close to 0.7 V vs. Li+/Li, some of these materials are promising as negative electrode materials for lithium ion battery.

引用

页码：66 / 75

页数：10

共 26 条

[1] TERNARY INTERMETALLIC PHASES OF LITHIUM, TRANSITION-METALS OF THE 4TH GROUP AND ELEMENTS OF THE 5TH MAIN GROUP WITH STATISTICAL METAL DISTRIBUTION IN THE CATION - SUBSTRUCTURE [J].

ADAM, A ;

SCHUSTER, HU .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 597 (06) :33-39

[2] CU3P as anode material for lithium ion battery:: powder morphology and electrochemical performances [J].

Bichat, MP ;

Politova, T ;

Pfeiffer, H ;

Tancret, F ;

Monconduit, L ;

Pascal, JL ;

Brousse, T ;

Favier, F .

JOURNAL OF POWER SOURCES, 2004, 136 (01) :80-87

[3]

Bichat MP, 2004, CHEM MATER, V16, P1002, DOI 10.1021/cm0351011

[4]

BICHAT MP, 2004, IN PRESS J ELECTROCH

[5] The LixVPn4 ternary phases (Pn = P, As):: Rigid networks for lithium intercalation/deintercalation [J].

Doublet, ML ;

Lemoigno, F ;

Gillot, F ;

Monconduit, L .

CHEMISTRY OF MATERIALS, 2002, 14 (10) :4126-4133

[6] TERNARY LITHIUM PHOSPHIDES HAVING ANTIFLUORINE STRUCTURE OR ITS DERIVATIVES - LI2N-3MNPN-1 WHERE M=BE, CD, SN [J].

ELMASLOU.A ;

MOTTE, JP ;

GLEITZER, C .

JOURNAL OF SOLID STATE CHEMISTRY, 1973, 7 (03) :250-254

[7] Carbon materials for lithium-ion rechargeable batteries [J].

Flandrois, S ;

Simon, B .

CARBON, 1999, 37 (02) :165-180

[8] STRUCTURE OF MONOCLINIC BLACK ZINC DIPHOSPHIDE, ZNP2 [J].

FLEET, ME ;

MOWLES, TA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (NOV) :1778-1779

[9] THERMODYNAMIC PROPERTIES OF BINARY LITHIUM-ZINC SYSTEM [J].

GASIOR, W ;

MOSER, Z .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1993, 90 (02) :387-397

[10] Ball milling synthesis of LixTiP4:: Improvement of the electrochemical performances [J].

Gillot, F ;

Bichat, MP ;

Favier, F ;

Morcrette, M ;

Tarascon, JM ;

Monconduit, L .

IONICS, 2003, 9 (1-2) :71-76

← 1 2 3 →