A convenient access to triarylphosphines with fluorous phase affinity

被引：53

作者：

Sinou, D

Pozzi, G

Hope, EG

Stuart, AM

机构：

[1] Univ Lyon 1, Lab Synthese Asymetr, CNRS, CPE Lyon, F-69622 Villeurbanne, France

[2] CNR, Ctr Sintesi & Stereochim Speciali Sistemi Organ, I-20133 Milan, Italy

[3] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

phosphines; phosphine oxides; perfluorinated solvent; perfluoroalkyl compounds;

D O I：

10.1016/S0040-4039(98)02537-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluorocarbon-soluble triarylphosphines with electronic properties similar to those of tris(p-methoxyphenyl)phosphine can be easily prepared through O-alkylation of tris(p-hydroxyphenyl)phosphine oxide and subsequent reduction with trichlorosilane. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：849 / 852

页数：4

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