Selective monoacetylation of diol compounds by Aspergillus niger lipase

被引：13

作者：

Hsiao, KF

Yang, FL

Wu, SH

Wang, KT

机构：

[1] ACAD SINICA,INST BIOL CHEM,TAIPEI 115,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 107,TAIWAN

来源：

BIOTECHNOLOGY LETTERS | 1996年 / 18卷 / 11期

关键词：

D O I：

10.1007/BF00129954

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The primary monoesters of diol compounds were formed exclusively in the reaction with vinyl acetate and Aspergillus niger lipase for 24 similar to 72 h. Various diol compounds which included 1,3-butanediol, 1,4-butanediol, 1,5-hexanediol, 1-phenyl-1,2-ethanediol, 1-phenyl-1,3-propanediol, 2, 3, or 4-hydroxybenzyl alcohol, methyl 2, 3-O-acetyl-D-glycopyranosides and phenyl 1-thio-beta-D-xylopyranoside have been examined and showed nearly 100% regioselectivity.

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收藏

页码：1277 / 1282

页数：6

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