Regiocontrolled carbometallation reactions of ynamides

被引：100

作者：

Chechik-Lankin, H ^{[1
]}

Livshin, S ^{[1
]}

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Lise Meitner Minerva Ctr Computat Quantum Chem, Dept Chem, Inst Catalysis Sci & Techonl, IL-32000 Haifa, Israel

来源：

SYNLETT | 2005年 / 13期

关键词：

carbocupration; carbomagnesiation; ynamides; regiochemistry; enamides;

D O I：

10.1055/s-2005-871962

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first carbocupration and copper-catalyzed carbomagnesiation reactions on diversely substituted ynamides is described here. This study shows that the linear regioisomer can be quantitatively obtained in the carbometallation reaction of N-substituted alkynes.

引用

页码：2098 / 2100

页数：3

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