Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

被引：250

作者：

Bertoli, Marcello ^{[1
]}

Choualeb, Aldjia ^{[1
]}

Lough, Alan J. ^{[2
]}

Moore, Brandon ^{[1
]}

Spasyuk, Denis ^{[1
]}

Gusev, Dmitry G. ^{[1
]}

机构：

[1] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada

[2] Univ Toronto, Dept Chem, Xray Lab, Toronto, ON M5S 3H6, Canada

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 13期

基金：

加拿大自然科学与工程研究理事会;

关键词：

N-ALKYLATION; PRIMARY AMINES; ACCEPTORLESS DEHYDROGENATION; TRANSFER HYDROGENATION; SELECTIVE SYNTHESIS; BORROWING HYDROGEN; PINCER COMPLEXES; AMIDE SYNTHESIS; KETONES; HETEROCYCLIZATION;

D O I：

10.1021/om200437n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C(2)H(4)PiPr(2))(2)] and OsH2-(CO)[HN(C(2)H(4)PiPr(2))(2)] possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.

引用

页码：3479 / 3482

页数：4

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