Tunable Catalytic Activity of Solid Solution Metal-Organic Frameworks in One-Pot Multicomponent Reactions

被引：143

作者：

Maria Aguirre-Diaz, Lina ^{[1
]}

Gandara, Felipe ^{[1
]}

Iglesias, Marta ^{[1
]}

Snejko, Natalia ^{[1
]}

Gutierrez-Puebla, Enrique ^{[1
]}

Angeles Monge, M. ^{[1
]}

机构：

[1] CSIC, ICMM, Dept Nuevas Arquitecturas Quim Mat, Madrid 28049, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 19期

关键词：

STORAGE;

D O I：

10.1021/jacs.5b02313

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aim of this research is to establish how metal-organic frameworks (MOPS) composed of More than one metal in equivalent crystallographic sites (solid solution MOFs) exhibit catalytic activity, which is tunable by virtue of the metal ions ratio. New MOFs with general formula [InxGa1-x(O2C2H4)(0.5)(hfipbb)] Were prepared by the combination of Ga and In. They are isostructural with their monometal counterparts, synthesized with Al, Ga., and In. Differences in their behavior as heterogeneous catalysts in the three-component, one pot Strecker reaction illustrate the potential of solid solution MOFs to provide the ability to address the various stages involved in the reaction mechanism.

引用

页码：6132 / 6135

页数：4

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