Synthesis and structure of a stable cyclic dialkylgermylene

被引：63

作者：

Kira, M ^{[1
]}

Ishida, S ^{[1
]}

Iwamoto, T ^{[1
]}

Ichinohe, M ^{[1
]}

Kabuto, C ^{[1
]}

Ignatovich, L ^{[1
]}

Sakurai, H ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 03期

关键词：

D O I：

10.1246/cl.1999.263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable cyclic dialkylgermylene(1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.

引用

页码：263 / 264

页数：2

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