Long-Range Ordered Single-Crystal Graphene on High-Quality Heteroepitaxial Ni Thin Films Grown on MgO(111)

被引:132
作者
Iwasaki, Takayuki [1 ]
Park, Hye Jin [1 ]
Konuma, Mitsuharu [1 ]
Lee, Dong Su [1 ]
Smet, Jurgen H. [1 ]
Starke, Ulrich [1 ]
机构
[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
关键词
Graphene; single crystal; large area; monolayer; heteroepitaxial growth; EPITAXIAL GRAPHENE; LARGE-AREA; MOLECULES; GRAPHITE; LAYERS;
D O I
10.1021/nl102834q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Large-area single crystal monolayer graphene is synthesized on Ni(111) thin films, which have flat terraces and no grain boundaries. The flat single-crystal Ni films are heteroepitaxially grown on MgO(111) substrates using a buffer layer technique. Low-energy electron diffraction and various spectroscopic methods reveal the long-range single crystallinity and uniform monolayer thickness of the graphene. when transferred onto an insulating wafer, continuous millimeter-scale single domain graphene is obtained.
引用
收藏
页码:79 / 84
页数:6
相关论文
共 30 条
[1]   METALORGANIC VAPOR-PHASE EPITAXIAL-GROWTH OF A HIGH-QUALITY GAN FILM USING AN AIN BUFFER LAYER [J].
AMANO, H ;
SAWAKI, N ;
AKASAKI, I ;
TOYODA, Y .
APPLIED PHYSICS LETTERS, 1986, 48 (05) :353-355
[2]   Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].
Berger, C ;
Song, ZM ;
Li, TB ;
Li, XB ;
Ogbazghi, AY ;
Feng, R ;
Dai, ZT ;
Marchenkov, AN ;
Conrad, EH ;
First, PN ;
de Heer, WA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916
[3]   SURFACTANT-INDUCED SUPPRESSION OF TWIN FORMATION DURING GROWTH OF FCC CO/CU SUPERLATTICES ON CU(111) [J].
CAMARERO, J ;
SPENDELER, L ;
SCHMIDT, G ;
HEINZ, K ;
DEMIGUEL, JJ ;
MIRANDA, R .
PHYSICAL REVIEW LETTERS, 1994, 73 (18) :2448-2451
[4]   Electrical Detection of DNA Hybridization with Single-Base Specificity Using Transistors Based on CVD-Grown Graphene Sheets [J].
Dong, Xiaochen ;
Shi, Yumeng ;
Huang, Wei ;
Chen, Peng ;
Li, Lain-Jong .
ADVANCED MATERIALS, 2010, 22 (14) :1649-+
[5]  
Emtsev KV, 2009, NAT MATER, V8, P203, DOI [10.1038/nmat2382, 10.1038/NMAT2382]
[6]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[7]   Atomic structure of monolayer graphite formed on Ni(111) [J].
Gamo, Y ;
Nagashima, A ;
Wakabayashi, M ;
Terai, M ;
Oshima, C .
SURFACE SCIENCE, 1997, 374 (1-3) :61-64
[8]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[9]   Tunable hybridization between electronic states of graphene and a metal surface [J].
Grueneis, Alexander ;
Vyalikh, Denis V. .
PHYSICAL REVIEW B, 2008, 77 (19)
[10]   Dynamics of graphene growth on a metal surface: a time-dependent photoemission study [J].
Grueneis, Alexander ;
Kummer, Kurt ;
Vyalikh, Denis V. .
NEW JOURNAL OF PHYSICS, 2009, 11