Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives

被引：119

作者：

Mahdi, Tayseer ^{[1
]}

Heiden, Zachariah M. ^{[1
]}

Grimme, Stefan ^{[2
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, D-53115 Bonn, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FREE CATALYTIC-HYDROGENATION; FRUSTRATED LEWIS PAIRS; INTRAMOLECULAR ARENE HYDROGENATION; ENANTIOSELECTIVE HYDROGENATION; HOMOGENEOUS HYDROGENATION; ASYMMETRIC HYDROGENATION; ORGANOMETALLIC COMPOUNDS; SUPPORTED RHODIUM; NIOBIUM; ACTIVATION;

D O I：

10.1021/ja300228a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H-2 and B(C6F5)(3), affording the corresponding N-cyclohexylammonium hydridoborate salts.

引用

页码：4088 / 4091

页数：4

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