Development of Composite Inorganic Building Blocks for MOFs

被引：217

作者：

Zheng, Shou-Tian ^{[2
]}

Wu, Tao ^{[1
]}

Chou, Chengtsung ^{[2
]}

Fuhr, Addis ^{[2
]}

Feng, Pingyun ^{[1
]}

Bu, Xianhui ^{[2
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 10期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORK; POROUS COORDINATION POLYMER; SELECTIVE CO2 CAPTURE; SINGLE-CRYSTAL; CLUSTERS; CARBON; TRANSFORMATION; SUBSTITUTION; SEPARATION; CHANNELS;

D O I：

10.1021/ja2118255

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general direction for diversifying metal organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity.

引用

页码：4517 / 4520

页数：4

共 54 条

[1] Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations [J].

An, Jihyun ;

Shade, Chad M. ;

Chengelis-Czegan, Demetra A. ;

Petoud, Stephane ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1220-1223

[2] Supermolecular building blocks (SBBs) and crystal design: 12-connected open frameworks based on a molecular cubohemioctahedron [J].

Cairns, Amy J. ;

Perman, Jason A. ;

Wojtas, Lukasz ;

Kravtsov, Victor Ch. ;

Alkordi, Mohamed H. ;

Eddaoudi, Mohamed ;

Zaworotko, Michael J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (05) :1560-+

[3] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].

Caskey, Stephen R. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+

[4] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[5] Heteropolynuclear metamagnet showing spin canting and single-crystal to single-crystal phase transformation [J].

Chen, Pang-Kuan ;

Che, Yun-Xia ;

Zheng, Ji-Min ;

Batten, Stuart R. .

CHEMISTRY OF MATERIALS, 2007, 19 (09) :2162-2167

[6] New mimic of zeolite: heterometallic organic host framework accommodating inorganic cations [J].

Chen, Yu-Biao ;

Kang, Yao ;

Zhang, Jian .

CHEMICAL COMMUNICATIONS, 2010, 46 (18) :3182-3184

[7]

Cheng YX, 2006, DALTON T, P4449, DOI 10.1039/b607782j

[8] Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks [J].

Choi, Hye-Sun ;

Suh, Myunghyun Paik .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (37) :6865-6869

[9] High thermal and chemical stability in pyrazolate-bridged metal-organic frameworks with exposed metal sites [J].

Colombo, Valentina ;

Galli, Simona ;

Choi, Hye Jin ;

Han, Ggoch Ddeul ;

Maspero, Angelo ;

Palmisano, Giovanni ;

Masciocchi, Norberto ;

Long, Jeffrey R. .

CHEMICAL SCIENCE, 2011, 2 (07) :1311-1319

[10] Nanoscale Metal-Organic Frameworks for Biomedical Imaging and Drug Delivery [J].

Della Rocca, Joseph ;

Liu, Demin ;

Lin, Wenbin .

ACCOUNTS OF CHEMICAL RESEARCH, 2011, 44 (10) :957-968

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