Development of Composite Inorganic Building Blocks for MOFs

被引：217

作者：

Zheng, Shou-Tian ^{[2
]}

Wu, Tao ^{[1
]}

Chou, Chengtsung ^{[2
]}

Fuhr, Addis ^{[2
]}

Feng, Pingyun ^{[1
]}

Bu, Xianhui ^{[2
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 10期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORK; POROUS COORDINATION POLYMER; SELECTIVE CO2 CAPTURE; SINGLE-CRYSTAL; CLUSTERS; CARBON; TRANSFORMATION; SUBSTITUTION; SEPARATION; CHANNELS;

D O I：

10.1021/ja2118255

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general direction for diversifying metal organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity.

引用

页码：4517 / 4520

页数：4

共 54 条

[31] Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids [J].

Parnham, Emily R. ;

Morris, Russell E. .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (10) :1005-1013

[32] New Microporous Metal-Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds [J].

Pramanik, Sanhita ;

Zheng, Chong ;

Zhang, Xiao ;

Emge, Thomas J. ;

Li, Jing .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4153-4155

[33] COMPLEXES OF 3RD GROUP ELEMENTS WITH [(EN)2M(III)(OH)2] LIGANDS (M=CR, CO) [J].

ROMINGER, F ;

MULLER, A ;

THEWALT, U .

CHEMISCHE BERICHTE, 1994, 127 (05) :797-804

[34] Magnetic metal-organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions [J].

Ryu, Dae Won ;

Lee, Woo Ram ;

Lee, Jin Wuk ;

Yoon, Jung Hee ;

Kim, Hyoung Chan ;

Koh, Eui Kwan ;

Hong, Chang Seop .

CHEMICAL COMMUNICATIONS, 2010, 46 (46) :8779-8781

[35] Al, Ga and In heterometallic wheels and their by-products [J].

Sanudo, E. Carolina ;

Muryn, Christopher A. ;

Helliwell, Madeleine A. ;

Timco, Grigore A. ;

Wernsdorfer, Wolfgang ;

Winpenny, Richard E. P. .

CHEMICAL COMMUNICATIONS, 2007, (08) :801-803

[36] Post-Synthesis Modification of a Metal-Organic Framework To Form Metallosalen-Containing MOF Materials [J].

Shultz, Abraham M. ;

Sarjeant, Amy A. ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Nguyen, SonBinh T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (34) :13252-13255

[37] Single-crystal structure validation with the program PLATON [J].

Spek, AL .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13

[38] Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods [J].

Sumida, Kenji ;

Horike, Satoshi ;

Kaye, Steven S. ;

Herm, Zoey R. ;

Queen, Wendy L. ;

Brown, Craig M. ;

Grandjean, Fernande ;

Long, Gary J. ;

Dailly, Anne ;

Long, Jeffrey R. .

CHEMICAL SCIENCE, 2010, 1 (02) :184-191

[39] Postsynthetic modification of metal-organic frameworks-a progress report [J].

Tanabe, Kristine K. ;

Cohen, Seth M. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :498-519

[40] Molecular magnetic materials based on 4d and 5d transition metals [J].

Wang, Xin-Yi ;

Avendano, Carolina ;

Dunbar, Kim R. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (06) :3213-3238

← 1 2 3 4 5 6 →