Platinum-free tungsten carbides as an efficient counter electrode for dye sensitized solar cells

被引:206
作者
Jang, Jum Suk [1 ]
Ham, Dong Jin [1 ]
Ramasamy, Easwaramoorthi [1 ]
Lee, Jinwoo [1 ]
Lee, Jae Sung [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang, South Korea
关键词
LOW-COST; MOLYBDENUM; PERFORMANCE; CATALYSTS; HYDROGEN; NICKEL; FILMS; WC;
D O I
10.1039/c0cc02247k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous tungsten carbides displayed an excellent solar conversion efficiency (7.01%) as a counter electrode for dye sensitized solar cells under 100 mW cm(-2), AM 1.5G illumination, which corresponded to ca. 85% of the efficiency of the conventional platinum electrode.
引用
收藏
页码:8600 / 8602
页数:3
相关论文
共 28 条
[1]   Electrocatalytic activity of some carburised nickel, tungsten and molybdenum compounds [J].
Barnett, CJ ;
Burstein, GT ;
Kucernak, ARJ ;
Williams, KR .
ELECTROCHIMICA ACTA, 1997, 42 (15) :2381-2388
[2]   Oxidation of hydrogen on WC at low temperature [J].
Bodoardo, S ;
Maja, M ;
Penazzi, N ;
Henn, FEG .
ELECTROCHIMICA ACTA, 1997, 42 (17) :2603-2609
[3]   Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids [J].
Fabregat-Santiago, Francisco ;
Bisquert, Juan ;
Palomares, Emilio ;
Otero, Luis ;
Kuang, Daibin ;
Zakeeruddin, Shaik M. ;
Gratzel, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (17) :6550-6560
[4]   Tungsten carbide microspheres as a noble-metal-economic electrocatalyst for methanol oxidation [J].
Ganesan, R ;
Lee, JS .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6557-6560
[5]   Platinized mesoporous tungsten carbide for electrochemical methanol oxidation [J].
Ganesan, Raman ;
Ham, Dong Jin ;
Lee, Jae Sung .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (10) :2576-2579
[6]   Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance [J].
Ham, Dong Jin ;
Kim, Young Kwon ;
Han, Seung Hyun ;
Lee, Jae Sung .
CATALYSIS TODAY, 2008, 132 (1-4) :117-122
[7]   Improvement of efficiency of dye-sensitized solar cells by reduction of internal resistance [J].
Han, LY ;
Koide, N ;
Chiba, Y ;
Islam, A ;
Komiya, R ;
Fuke, N ;
Fukui, A ;
Yamanaka, R .
APPLIED PHYSICS LETTERS, 2005, 86 (21) :1-3
[8]   Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells [J].
Hauch, A ;
Georg, A .
ELECTROCHIMICA ACTA, 2001, 46 (22) :3457-3466
[9]   Preparation of functionalized and non-functionalized fullerene thin films on ITO glasses and the application to a counter electrode in a dye-sensitized solar cell [J].
Hino, T ;
Ogawa, Y ;
Kuramoto, N .
CARBON, 2006, 44 (05) :880-887
[10]   High-performance carbon counter electrode for dye-sensitized solar cells [J].
Imoto, K ;
Takahashi, K ;
Yamaguchi, T ;
Komura, T ;
Nakamura, J ;
Murata, K .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 79 (04) :459-469