Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

被引：51

作者：

Boyer, Cyrille ^{[1
]}

Soeriyadi, Alexander H. ^{[1
]}

Roth, Peter J. ^{[1
]}

Whittaker, Michael R. ^{[1
]}

Davis, Thomas P. ^{[1
]}

机构：

[1] Univ New S Wales, CAMD, Sch Chem Engn, Sydney, NSW 2052, Australia

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 04期

关键词：

TRANSFER RADICAL POLYMERIZATION; TELECHELIC OLIGOMERS; RAFT-POLYMERS; POLYSTYRENE; MACROMONOMERS; DISULFIDE; ROUTE;

D O I：

10.1039/c0cc03815f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene "click" reactions.

引用

页码：1318 / 1320

页数：3

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