Time evolution of nucleation and vertical growth of carbon nanotubes during plasma-enhanced chemical vapor deposition

被引:8
作者
Jeong, GH [1 ]
Satake, N
Kato, T
Hirata, T
Hatakeyama, R
Tohji, K
机构
[1] Tohoku Univ, Dept Elect Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Dept Geosci & Technol, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS | 2003年 / 42卷 / 11A期
关键词
carbon nanotube; plasma-enhanced chemical vapor deposition; methane-hydrogen gas mixture; time evolution; nucleation; vertical growth mechanism;
D O I
10.1143/JJAP.42.L1340
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have investigated the time evolution during nanotube growth and proposed the growth mechanism in order to understand the effects of plasma proper-ties on nanotube formation and controlled growth in the case of plasma-enhanced chemical vapor deposition. The nucleation process of multi-walled carbon nanotubes (MWNTs) firstly takes place through catalyst tip formation. MWNTs grow with a wide diameter distribution at the initial growth stage and finally attain similar diameters as growth proceeds. In addition, ion flux and bombardment energy need to be optimized during the nanotube growth for vertical alignment and a highly crystallized structure.
引用
收藏
页码:L1340 / L1342
页数:3
相关论文
共 12 条
[1]   Plasma-induced alignment of carbon nanotubes [J].
Bower, C ;
Zhu, W ;
Jin, SH ;
Zhou, O .
APPLIED PHYSICS LETTERS, 2000, 77 (06) :830-832
[2]   Low-temperature synthesis multiwalled carbon nanotubes by microwave plasma chemical vapor deposition using CH4-CO2 gas mixture [J].
Chen, M ;
Chen, CM ;
Shi, SC ;
Chen, CF .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2003, 42 (2A) :614-619
[3]   Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition [J].
Chhowalla, M ;
Teo, KBK ;
Ducati, C ;
Rupesinghe, NL ;
Amaratunga, GAJ ;
Ferrari, AC ;
Roy, D ;
Robertson, J ;
Milne, WI .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5308-5317
[4]   Self-oriented regular arrays of carbon nanotubes and their field emission properties [J].
Fan, SS ;
Chapline, MG ;
Franklin, NR ;
Tombler, TW ;
Cassell, AM ;
Dai, HJ .
SCIENCE, 1999, 283 (5401) :512-514
[5]   Growth of well-aligned carbon nanotubes on nickel by hot-filament-assisted dc plasma chemical vapor deposition in a CH4/H2 plasma [J].
Hayashi, Y ;
Negishi, T ;
Nishino, S .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 2001, 19 (04) :1796-1799
[6]   Magnetron-type radio-frequency plasma control yielding vertically well-aligned carbon nanotube growth [J].
Hirata, T ;
Satake, N ;
Jeong, GH ;
Kato, T ;
Hatakeyama, R ;
Motomiya, K ;
Tohji, K .
APPLIED PHYSICS LETTERS, 2003, 83 (06) :1119-1121
[7]   Low temperature synthesis of aligned carbon nanotubes by inductively coupled plasma chemical vapor deposition using pure methane [J].
Honda, S ;
Katayama, M ;
Lee, KY ;
Ikuno, T ;
Ohkura, S ;
Oura, K ;
Furuta, H ;
Hirao, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2003, 42 (4B) :L441-L443
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]   Experimental study of fullerene-family formation using radio-frequency-discharge reactive plasmas [J].
Ishida, H ;
Satake, N ;
Jeong, GH ;
Abe, Y ;
Hirata, T ;
Hatakeyama, R ;
Tohji, K ;
Motomiya, K .
THIN SOLID FILMS, 2002, 407 (1-2) :26-31
[10]   UNRAVELING NANOTUBES - FIELD-EMISSION FROM AN ATOMIC WIRE [J].
RINZLER, AG ;
HAFNER, JH ;
NIKOLAEV, P ;
LOU, L ;
KIM, SG ;
TOMANEK, D ;
NORDLANDER, P ;
COLBERT, DT ;
SMALLEY, RE .
SCIENCE, 1995, 269 (5230) :1550-1553