Synthesis of Nitrogen-Doped Graphene Using Embedded Carbon and Nitrogen Sources

被引:736
作者
Zhang, Chaohua [1 ]
Fu, Lei [1 ]
Liu, Nan [1 ]
Liu, Minhao [2 ]
Wang, Yayu [2 ]
Liu, Zhongfan [1 ]
机构
[1] Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Ctr Nanochem,Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn,Acad Adv Interdisciplinary S, Beijing 100871, Peoples R China
[2] Tsinghua Univ, Dept Phys, Beijing 100084, Peoples R China
关键词
COKING RESISTANCE; BORON; GRAPHITE; NITRIDE;
D O I
10.1002/adma.201004110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile strategy to grow nitrogen-doped graphene using embedded nitrogen and carbon in metal substrate via a segregation method is reported. As doping is concurrently carried out in the segregation process of the carbon species, N atoms can be substitutionally doped into the graphene lattice. This approach allows precise control of the doping degree and location, which enables growing various heterojunctions at the desired location. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1020 / 1024
页数:5
相关论文
共 33 条
[21]   Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells [J].
Qu, Liangti ;
Liu, Yong ;
Baek, Jong-Beom ;
Dai, Liming .
ACS NANO, 2010, 4 (03) :1321-1326
[22]   Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application [J].
Reddy, Arava Leela Mohana ;
Srivastava, Anchal ;
Gowda, Sanketh R. ;
Gullapalli, Hemtej ;
Dubey, Madan ;
Ajayan, Pulickel M. .
ACS NANO, 2010, 4 (11) :6337-6342
[23]  
Schwierz F, 2010, NAT NANOTECHNOL, V5, P487, DOI [10.1038/NNANO.2010.89, 10.1038/nnano.2010.89]
[24]   Nitrogen-doped graphene and its electrochemical applications [J].
Shao, Yuyan ;
Zhang, Sheng ;
Engelhard, Mark H. ;
Li, Guosheng ;
Shao, Guocheng ;
Wang, Yong ;
Liu, Jun ;
Aksay, Ilhan A. ;
Lin, Yuehe .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7491-7496
[25]   Simple Method of Preparing Graphene Flakes by an Arc-Discharge Method [J].
Subrahmanyam, K. S. ;
Panchakarla, L. S. ;
Govindaraj, A. ;
Rao, C. N. R. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (11) :4257-4259
[26]   Modification of graphene properties due to electron-beam irradiation [J].
Teweldebrhan, D. ;
Balandin, A. A. .
APPLIED PHYSICS LETTERS, 2009, 94 (01)
[27]   Tuning nitrogen functionalities in catalytically grown nitrogen-containing carbon nanotubes [J].
van Dommele, S. ;
Romero-Izquirdo, A. ;
Brydson, R. ;
de Jong, K. P. ;
Bitter, J. H. .
CARBON, 2008, 46 (01) :138-148
[28]   N-Doping of Graphene Through Electrothermal Reactions with Ammonia [J].
Wang, Xinran ;
Li, Xiaolin ;
Zhang, Li ;
Yoon, Youngki ;
Weber, Peter K. ;
Wang, Hailiang ;
Guo, Jing ;
Dai, Hongjie .
SCIENCE, 2009, 324 (5928) :768-771
[29]   Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing [J].
Wang, Ying ;
Shao, Yuyan ;
Matson, Dean W. ;
Li, Jinghong ;
Lin, Yuehe .
ACS NANO, 2010, 4 (04) :1790-1798
[30]  
WEI ADC, 2009, ADV MATER, V21, P4726