Direct pseudopotential calculation of exciton Coulomb and exchange energies in semiconductor quantum dots

被引:230
作者
Franceschetti, A
Zunger, A
机构
[1] National Renewable Energy Laboratory, Golden, CO
关键词
D O I
10.1103/PhysRevLett.78.915
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The effects of electron-hole interaction on the exciton energy of semiconductor quantum dots are calculated using pseudopotential wave functions. A comparison with the widely used, but never tested, effective-mass approximation (EMA) shows that the electron-hole Coulomb energy is significantly (similar to 40%) overestimated by the EMA, and that the scaling with the dot size R is sublinear in 1/R. The exchange splitting is much smaller than the Coulomb energy, and in the case of CdSe quantum dots shows significant deviations from the 1/R(3) scaling predicted by the EMA.
引用
收藏
页码:915 / 918
页数:4
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