Silver-mediated fluorination of aryl silanes

被引：90

作者：

Tang, Pingping ^{[1
]}

Ritter, Tobias ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

TETRAHEDRON | 2011年 / 67卷 / 24期

基金：

美国国家科学基金会;

关键词：

Silver oxide; Fluorine; Aryl silane; Selectfluor; CROSS-COUPLING REACTIONS; REDUCTIVE ELIMINATION; PALLADIUM(0)-CATALYZED SILYLATION; ELECTROPHILIC FLUORINATION; FUNCTIONALIZED ARYL; EFFICIENT SYNTHESIS; PALLADIUM; HALIDES; BOND; ARYLTRIETHOXYSILANES;

D O I：

10.1016/j.tet.2011.02.077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag2O as readily available, inexpensive silver source, which can be recovered. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：4449 / 4454

页数：6

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