Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution

被引:204
作者
Arrabal, R. [1 ]
Pardo, A. [1 ]
Merino, M. C. [1 ]
Mohedano, M. [1 ]
Casajus, P. [1 ]
Paucar, K. [2 ]
Garces, G. [3 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Fis, Dept Ciencia Mat, E-28040 Madrid, Spain
[2] Univ Nacl Ingn, Fac Ingn Quim & Text, Lima, Peru
[3] Ctr Nacl Invest Met CSIC, Madrid 28040, Spain
关键词
Magnesium; Polarization; Weight loss; Pitting corrosion; MECHANICAL-PROPERTIES; PURE MAGNESIUM; MICROSTRUCTURE; RESISTANCE; PROTECTION; NEODYMIUM; CHLORIDE; OXIDES;
D O I
10.1016/j.corsci.2011.10.033
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
The corrosion performance of AM50 and AZ91D alloys containing up to 1.5 wt.% Nd was investigated by electrochemical and gravimetric measurements in 3.5 wt.% NaCl at 22 degrees C. The alloys were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and surface potential maps. In Nd-containing alloys, formation of Al2Nd and Al-Mn-Nd intermetallic compounds reduced the volume fraction and modified the morphology of the beta-Mg17Al12 phase. The addition of Nd improved the corrosion resistance of the alloys due to increased passivity of the surface film and suppression of micro-galvanic couples. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:301 / 312
页数:12
相关论文
共 42 条
[1]
Analysis of the electrochemical reaction behavior of alloy AZ91 by EIS technique in H3PO4/KOH buffered K2SO4 solutions [J].
Anik, Mustafa ;
Celikten, Gizem .
CORROSION SCIENCE, 2007, 49 (04) :1878-1894
[2]
Corrosion behaviour of a magnesium matrix composite with a silicate plasma electrolytic oxidation coating [J].
Arrabal, R. ;
Pardo, A. ;
Merino, M. C. ;
Mohedano, M. ;
Casajus, P. ;
Matykina, E. ;
Skeldon, P. ;
Thompson, G. E. .
CORROSION SCIENCE, 2010, 52 (11) :3738-3749
[3]
The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions [J].
Baril, G ;
Pébère, N .
CORROSION SCIENCE, 2001, 43 (03) :471-484
[4]
An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions [J].
Baril, Genevieve ;
Galicia, Gonzalo ;
Deslouis, Claude ;
Pebere, Nadine ;
Tribollet, Bernard ;
Vivier, Vincent .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) :C108-C113
[5]
Magnesium secondary alloys: Alloy design for magnesium alloys with improved tolerance limits against impurities [J].
Blawert, C. ;
Fechner, D. ;
Hoeche, D. ;
Heitmann, V. ;
Dietzel, W. ;
Kainer, K. U. ;
Zivanovic, P. ;
Scharf, C. ;
Ditze, A. ;
Groebner, J. ;
Schmid-Fetzer, R. .
CORROSION SCIENCE, 2010, 52 (07) :2452-2468
[6]
AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution [J].
Chen, Jian ;
Wang, Jianqiu ;
Han, Enhou ;
Dong, Junhua ;
Ke, Wei .
ELECTROCHIMICA ACTA, 2007, 52 (09) :3299-3309
[7]
Dargush M.S., 1997, T 19 INT CAST C, P131
[8]
Influence of cerium on the microstructure, mechanical properties and corrosion resistance of magnesium alloy [J].
Fan, Yu ;
Wu, Guohua ;
Zhai, Chunquan .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 433 (1-2) :208-215
[9]
Protective coatings on magnesium and its alloys - a critical review [J].
Gray, JE ;
Luan, B .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 336 (1-2) :88-113
[10]
Huang ZH., 2005, ACTA METALL SIN, V18, P129