Exploring the nickel-catalyzed oxidation of alkenes:: A diamination by sulfamide transfer

被引：112

作者：

Muniz, Kilian ^{[1
]}

Streuff, Jan ^{[1
]}

Hoevelmann, Claas H. ^{[1
]}

Nunez, Ana ^{[1
]}

机构：

[1] Univ Louis Pasteur, Inst Chem, UMR 7177, F-67070 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 37期

关键词：

diamines; homogeneous catalysis; nickel; oxidation; sulfamides;

D O I：

10.1002/anie.200702160

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Nickel can oxidize, too! Nickel (II) salts such as nickel chloride and nickel acetylacetonate catalyze the intramolecular diamination of alkenes with urea and guanidine derivatives as well as sulfamides as nitrogen sources. The latter represent particularly attractive starting materials, as they allow for a selective and convenient liberation of the diamines from the oxidation products (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7125 / 7127

页数：3

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