The characteristic red chemiluminescence from reactions with acidic potassium permanganate: further spectroscopic evidence for a manganese(II) emitter

被引:58
作者
Adcock, Jacqui L. [1 ]
Francis, Paul S. [1 ]
Smith, Trevor A. [2 ]
Barnett, Neil W. [1 ]
机构
[1] Deakin Univ, Sch Life & Environm Sci, Geelong, Vic 3217, Australia
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
关键词
D O I
10.1039/b714147e
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A direct comparison of the laser-induced photoluminescence of manganese(II) with the chemiluminescence from the reaction between acidic potassium permanganate and sodium borohydride was used to confirm that the characteristic red emission from this widely used chemiluminescence reagent emanates from an electronically excited manganese(II) species.
引用
收藏
页码:49 / 51
页数:3
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