Ligand electronic effects on rates of copper mediated atom transfer radical cyclisation and polymerisation

被引：34

作者：

Clark, AJ ^{[1
]}

Battle, GM

Heming, AM

Haddleton, DM

Bridge, A

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Aventis Pharma Ltd, Dagenham RM10 7XS, Essex, England

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

radicals and radical reactions; cyclisations; copper and compounds; polymers;

D O I：

10.1016/S0040-4039(01)00061-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2003 / 2005

页数：3

共 25 条

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[7] The influence of benzylic protection and allylic substituents on the CuCl-TMEDA catalyzed rearrangement of N-allyl-N-benzyl-2,2-dihaloamides to γ-lactams.: Application to the stereoselective synthesis of pilolactam.
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