MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF

被引：496

作者：

Llabres i Xamena, Francesc X. ^{[1
]}

Abad, Alberto ^{[1
]}

Corma, Avelino ^{[1
]}

Garcia, Hermenegildo ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

来源：

JOURNAL OF CATALYSIS | 2007年 / 250卷 / 02期

关键词：

metal-organic framework; Pd catalysts; shape-selectivity; alcohol oxidation; Suzuki C-C coupling; olefin hydrogenation;

D O I：

10.1016/j.jcat.2007.06.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A palladium-containing metal-organic framework (Pd-MOF) was found to be an active catalyst for alcohol oxidation, Suzuki C-C coupling, and olefin hydrogenation. The MOF structure is preserved throughout catalysis, and the material is reusable. The Pd-MOF demonstrates remarkable shape-selectivity for olefin conversion. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：294 / 298

页数：5

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