Effect of a silane coupling agent on the properties of white rice husk ash-polypropylene/natural rubber composites

被引:63
作者
Ismail, H [1 ]
Mega, L [1 ]
Khalil, HPSA [1 ]
机构
[1] Univ Sains Malaysia, Sch Ind Technol, Minden 11800, Penang, Malaysia
关键词
silane coupling agent; white rice husk ash; polypropylene; natural rubber; mechanical properties and water absorption;
D O I
10.1002/pi.673
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
White rice husk ash (WRHA)-polypropylene (PP)/natural rubber (NR) composites were prepared using a Brabender Plasticorder at 180 degreesC and a rotor speed of 50 rev min(-1), The mechanical and water-absorption properties were studied. The incorporation of WRHA into the PP/NR matrix has resulted in the improvement of the tensile modulus; however, the tensile strength, elongation at break and stress at yield decreased with increasing WRHA loading. Poor filler matrix interactions are believed to be responsible for the decrease in the properties. Incorporation of a silane coupling agent, 3-aminopropyl triethoxysilane (3-APE), improved tensile modulus, tensile strength and stress at yield of the composites. Water-absorption studies indicate that the use of the coupling agent reduced the amount of water absorbed by the composites. (C) 2001 Society of Chemical Industry.
引用
收藏
页码:606 / 611
页数:6
相关论文
共 25 条
[11]   White rice husk ash filled natural rubber compounds: the effect of multifunctional additive and silane coupling agents [J].
Ismail, H ;
Nasaruddin, MN ;
Ishiaku, US .
POLYMER TESTING, 1999, 18 (04) :287-298
[12]   Epoxidized natural rubber compounds: Effect of vulcanization systems and fillers [J].
Ismail, H ;
Ishiaku, US ;
Arinab, AR ;
Ishak, ZAM .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1998, 37 (04) :469-481
[13]  
Ismail H., 1997, INT J POLYM MATER, V36, P39, DOI 10.1080/00914039708044136
[14]   THE RUBBER PARTICLE-SIZE DEPENDENCE OF CRAZING IN POLYPROPYLENE [J].
JANG, BZ ;
UHLMANN, DR ;
VANDERSANDE, JB .
POLYMER ENGINEERING AND SCIENCE, 1985, 25 (10) :643-651
[15]   Morphology, mechanical and thermal behavior of acrylate rubber/fluorocarbon elastomer/polyacrylate blends [J].
Kader, MA ;
Bhowmick, AK ;
Inoue, T ;
Chiba, T .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (08) :1503-1513
[16]   THE EFFICIENCY OF CELLULOSIC FILLERS IN COMMON THERMOPLASTICS .1. FILLING WITHOUT PROCESSING AIDS OR COUPLING AGENTS [J].
KLASON, C ;
KUBAT, J ;
STROMVALL, HE .
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1984, 10 (03) :159-187
[17]   MECHANICAL-PROPERTIES OF ISOTACTIC POLYPROPYLENE WOOD FLOUR COMPOSITES [J].
MAITI, SN ;
SUBBARAO, R .
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1991, 15 (01) :1-16
[18]   INFLUENCE OF COUPLING AGENTS AND TREATMENTS ON THE MECHANICAL-PROPERTIES OF CELLULOSE FIBER-POLYSTYRENE COMPOSITES [J].
MALDAS, D ;
KOKTA, BV ;
DANEAULT, C .
JOURNAL OF APPLIED POLYMER SCIENCE, 1989, 37 (03) :751-775
[19]  
MANSON JA, 1976, POLYM BLENDS COMPOSI, pCH12
[20]  
Nielsen LE, 1974, MECH PROPERTIES POLY, V2, P405