Structurally defined reactions of sodium TMP-zincate with nitrile compounds: Synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products

被引：35

作者：

Clegg, William ^{[2
]}

Dale, Sophie H. ^{[2
]}

Hevia, Eva ^{[1
]}

Hogg, Lorna M. ^{[1
]}

Honeyman, Gordon W. ^{[1
]}

Mulvey, Robert E. ^{[1
]}

O'Hara, Charles T. ^{[1
]}

Russo, Luca ^{[2
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Newcastle Upon Tyne, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 04期

关键词：

ion pairs; metalation; nitriles; sodium; zinc;

D O I：

10.1002/anie.200704341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：731 / 734

页数：4

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