Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

被引：155

作者：

Ackermann, Lutz ^{[1
]}

Diers, Emelyne ^{[1
]}

Manvar, Atul ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 04期

关键词：

PHOSPHINE OXIDES; ARYL; FUNCTIONALIZATION; ACTIVATION; PRELIGANDS; PALLADIUM; PHENOLS; BROMIDES; SYSTEM;

D O I：

10.1021/ol3000876

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.

引用

页码：1154 / 1157

页数：4

共 60 条

[51] Preparative Scale Synthesis of the Biaryl Core of Anacetrapib via a Ruthenium-Catalyzed Direct Arylation Reaction: Unexpected Effect of Solvent Impurity on the Arylation Reaction
Ouellet, Stephane G.
Roy, Amelie
Molinaro, Carmela
Angelaud, Remy
Marcoux, Jean-Francois
O'Shea, Paul D.
Davies, Ian W.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (05) : 1436 - 1439
[52] Direct arylation of arene C-H bonds by cooperative action of NHCarbene-Ruthenium(II) catalyst and carbonate via proton abstraction mechanism
Ozdemir, Ismail
Demir, Serpil
Cetinkaya, Bekir
Gourlaouen, Christophe
Maseras, Feliu
Bruneau, Christian
Dixneuf, Pierre H.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (04) : 1156 - +
[53] Catalytic direct arylation of heteroaromatic compounds
Satoh, Tetsuya
Miura, Masahiro
[J]. CHEMISTRY LETTERS, 2007, 36 (02) : 200 - 205
[54] Synthesis of Angiotensin II Receptor Blockers by Means of a Catalytic System for C-H Activation
Seki, Masahiko
Nagahama, Masaki
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (24) : 10198 - 10206
[55] Highly Efficient Catalytic System for C-H Activation: A Practical Approach to Angiotensin II Receptor Blockers
Seki, Masahiko
[J]. ACS CATALYSIS, 2011, 1 (06): : 607 - 610
[56] C-H Bond Functionalization of Arylpyrimidines Catalyzed by an in situ Generated Ruthenium(II) Carboxylate System and the Construction of Tris(heteroaryl)-Substituted Benzenes
Stefane, Bogdan
Fabris, Jan
Pozgan, Franc
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 2011 (19) : 3474 - 3481
[57] Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation
Sun, Chang-Liang
Li, Bi-Jie
Shi, Zhang-Jie
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (05) : 677 - 685
[58] Construction of Nitrogen-Containing Heterocycles by C-H Bond Functionalization
Thansandote, Praew
Lautens, Mark
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (24) : 5874 - 5883
[59] Catalytic Dehydrogenative Cross-Coupling: Forming Carbon-Carbon Bonds by Oxidizing Two Carbon-Hydrogen Bonds
Yeung, Charles S.
Dong, Vy M.
[J]. CHEMICAL REVIEWS, 2011, 111 (03) : 1215 - 1292
[60] A Highly Efficient Ruthenium(II) Catalyst with (1,2-Diarylvinyl)phosphine Ligands for Direct Ortho Arylation of 2-Arylpyridine with Aryl Chlorides
Yu, Bingran
Yan, Xiaoyu
Wang, Song
Tang, Ning
Xi, Chanjuan
[J]. ORGANOMETALLICS, 2010, 29 (14) : 3222 - 3226

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