Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

被引：155

作者：

Ackermann, Lutz ^{[1
]}

Diers, Emelyne ^{[1
]}

Manvar, Atul ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 04期

关键词：

PHOSPHINE OXIDES; ARYL; FUNCTIONALIZATION; ACTIVATION; PRELIGANDS; PALLADIUM; PHENOLS; BROMIDES; SYSTEM;

D O I：

10.1021/ol3000876

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.

引用

页码：1154 / 1157

页数：4

共 60 条

[11] Ruthenium-Catalyzed Oxidative Annulation by Cleavage of C-H/N-H Bonds
Ackermann, Lutz
Lygin, Alexander V.
Hofmann, Nora
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (28) : 6379 - 6382
[12] Ruthenium-Catalyzed Direct C-H Bond Arylations of Heteroarenes
Ackermann, Lutz
Lygin, Alexander V.
[J]. ORGANIC LETTERS, 2011, 13 (13) : 3332 - 3335
[13] Carboxylate-Assisted Transition-Metal-Catalyzed C-H Bond Functionalizations: Mechanism and Scope
Ackermann, Lutz
[J]. CHEMICAL REVIEWS, 2011, 111 (03) : 1315 - 1345
[14] Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines
Ackermann, Lutz
Hofmann, Nora
Vicente, Ruben
[J]. ORGANIC LETTERS, 2011, 13 (07) : 1875 - 1877
[15] Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations
Ackermann, Lutz
[J]. ISRAEL JOURNAL OF CHEMISTRY, 2010, 50 (5-6) : 652 - 663
[16] Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts
Ackermann, Lutz
Vicente, Ruben
Potukuchi, Harish K.
Pirovano, Valentina
[J]. ORGANIC LETTERS, 2010, 12 (21) : 5032 - 5035
[17] Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C-H bond functionalization nexus
Ackermann, Lutz
Potukuchi, Harish Kumar
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2010, 8 (20) : 4503 - 4513
[18] Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations
Ackermann, Lutz
Novak, Petr
Vicente, Ruben
Pirovano, Valentina
Potukuchi, Harish K.
[J]. SYNTHESIS-STUTTGART, 2010, (13): : 2245 - 2253
[19] Transition-metal-catalyzed direct arylations via C-H bond cleavages
Ackermann, Lutz
[J]. PURE AND APPLIED CHEMISTRY, 2010, 82 (07) : 1403 - 1413
[20] Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages
Ackermann, Lutz
Vicente, Ruben
[J]. C-H ACTIVATION, 2010, 292 : 211 - 229

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