A highly efficient synthesis of unnatural L-sugars from D-ribose

被引：53

作者：

Yun, M

Moon, HR ^{[1
]}

Kim, HO

Choi, WJ

Kim, YC

Park, CS

Jeong, LS

机构：

[1] Pusan Natl Univ, Coll Pharm, Pusan 609735, South Korea

[2] Ewha Womans Univ, Coll Pharm, Med Chem Lab, Seoul 120750, South Korea

[3] Gwaangju Inst Sci & Technol, Dept Life Sci, Kwangju 500712, South Korea

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 35期

关键词：

L-ribose; L-apiose; cis-dihydroxylation; hydroxymethylation;

D O I：

10.1016/j.tetlet.2005.06.117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A preparative and short synthesis of L-ribose and L-apiose was accomplished starting from D-ribose via stereoselective cis-dihydroxylation and C2-hydroxymethylation, respectively. These L-sugars can serve as versatile intermediates for the synthesis Of L-nucleosides. (c) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：5903 / 5905

页数：3

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