Efficient generation of stable adducts of Si(II) dihydride using a donor-acceptor approach

被引：96

作者：

Al-Rafia, S. M. Ibrahim ^{[1
]}

Malcolm, Adam C. ^{[1
]}

McDonald, Robert ^{[1
]}

Ferguson, Michael J. ^{[1
]}

Rivard, Eric ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 09期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

N-HETEROCYCLIC CARBENE; BASE-STABILIZED DICHLOROSILYLENE; TRANSITION-METAL-COMPLEXES; RHODIUM(I) COMPLEXES; SILICON(II) HYDRIDE; SILYLENE; REACTIVITY; CHEMISTRY; HYDROSILYLATION; LIGANDS;

D O I：

10.1039/c2cc17101e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable Si(II) dihydride complex, IPr center dot SiH(2)center dot BH(3) (IPr = [(HCNDipp)(2)C:]; Dipp = 2,6-(i)Pr(2)C(6)H(3)), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported.

引用

页码：1308 / 1310

页数：3

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