SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

被引：217

作者：

Filippou, Alexander C. ^{[1
]}

Chernov, Oleg ^{[1
]}

Schnakenburg, Gregor ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 31期

关键词：

carbene ligands; density functional calculations; donor-acceptor systems; silicon; silylenes; NATURAL RESONANCE THEORY; MOLECULAR-STRUCTURE; GERMANIUM(II) AZIDES; SILICON DICHLORIDE; DIVALENT SILICON; COMPLEXES; CHEMISTRY; DECAMETHYLSILICOCENE; SPECTROSCOPY; DIBROMIDE;

D O I：

10.1002/anie.200902431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silylene with a carbene carabiner: The synthesis, structure, and some reactions of a stable carbene adduct of dibromosilylene, SiBr2(Idipp) (see picture; Idipp=1,3-bis(2,6-diisopropylphenyl)- imidazol-2-ylidene), are described. SiBr2(Idipp) was characterized by X-ray crystallography, NMR spectroscopy, and theoretical methods. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5687 / 5690

页数：4

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