Simultaneous copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) and living radical polymerization

被引：140

作者：

Geng, Jin ^{[1
]}

Lindqvist, Josefina ^{[1
]}

Mantovani, Giuseppe ^{[1
]}

Haddleton, David M. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 22期

关键词：

click chemistry; copper; cycloaddition; one-pot process; polymerization;

D O I：

10.1002/anie.200800179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) All in one: CuBr/iminopyridine systems can catalyze simultaneously both copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC, "click") and living radical polymerization (LRP) processes (see scheme). The relative rate of the two processes can be tailored by a judicious choice of the reaction conditions (solvent, temperature, [CuBr] 0) leading to the development of a potentially very efficient synthetic route to well-defined functional polymers. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4180 / 4183

页数：4

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