Conjugated Copolymers of Vinylene Flanked Naphthalene Diimide

被引：52

作者：

Fei, Zhuping ^{[1
,2
]}

Han, Yang ^{[1
,2
,3
]}

Martin, Jaime ^{[2
,4
]}

Scholes, Fiona H. ^{[5
]}

Al-Hashimi, Mohammed ^{[7
]}

AlQaradawi, Siham Y. ^{[6
]}

Stingelin, Natalie ^{[2
,4
]}

Anthopoulos, Thomas D. ^{[2
,3
]}

Heeney, Martin ^{[1
,2
]}

机构：

[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England

[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England

[3] Imperial Coll London, Dept Phys, London SW7 2AZ, England

[4] Imperial Coll London, Dept Mat, London SW7 2AZ, England

[5] CSIRO Mfg, Private Bag 10, Clayton, Vic 3169, Australia

[6] Qatar Univ, Dept Chem & Earth Sci, POB 2713, Doha, Qatar

[7] Texas A&M Univ Qatar, Dept Chem, POB 23874, Doha, Qatar

来源：

MACROMOLECULES | 2016年 / 49卷 / 17期

关键词：

FIELD-EFFECT TRANSISTORS; CHANNEL ORGANIC TRANSISTORS; HIGH-ELECTRON-MOBILITY; POLYMER SOLAR-CELLS; N-CHANNEL; CHARGE-TRANSPORT; SEMICONDUCTING POLYMERS; HIGH-PERFORMANCE; DIRECT ARYLATION; HIGH HOLE;

D O I：

10.1021/acs.macromol.6b01423

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the synthesis of a novel naphthalene diimide (NDI) monomer containing two (tributylstannyl)vinyl groups. The utility of this building block is demonstrated by its copolymerization with five different electron-rich comonomers under Stille conditions. The resulting high molecular weight polymers show red-shifted optical absorptions in comparison to the analogous polymers without the vinylene spacer and a significant increase in the intensity of the low-energy intramolecular charge transfer band. The polymers all exhibit ambipolar behavior in bottom-gate, top-contact organic thin-film transistors. The insertion of a solution-processed barium hydroxide layer between the polymer and the gold electrode led to unipolar behavior with improved electron mobilities.

引用

页码：6384 / 6393

页数：10

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