Clar's Aromatic Sextet and p-Electron Distribution in Nanographene

被引：31

作者：

Fujii, Shintato ^{[1
]}

Enoki, Toshiaki ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 29期

关键词：

electronic structure; graphene; oxidation; scanning probe microscopy; surface analysis; METAL WORK FUNCTION; GRAPHENE OXIDE; CHEMICAL-STRUCTURE; CARBON NANOTUBES; HYDROCARBONS; JUNCTIONS; TEMPERATURE; NANORIBBONS; CHEMISTRY; BENZENE;

D O I：

10.1002/anie.201202560

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cut into pieces: The π-electron distribution in nanographene fragments isolated between oxidized graphene areas is investigated using scanning probe microscopy (see picture). The edge-shape-dependent localization and migration of the Clar sextet explains the observed π-state distributions and enables investigation of the electronic properties. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7236 / 7241

页数：6

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