Ruphos-mediated Suzuki cross-coupling of secondary alkyl trifluoroborates

被引：53

作者：

van den Hoogenband, Adri ^{[1
]}

Lange, Jos H. M. ^{[1
]}

Terpstra, Jan Willem ^{[1
]}

Koch, Melle ^{[2
]}

Visser, Gerben M. ^{[2
]}

Visser, Martin ^{[1
]}

Korstanje, Ties J. ^{[1
]}

Jastrzebski, Johann T. B. H. ^{[3
]}

机构：

[1] Solvay Pharmaceut, Res Labs, NL-1381 CP Weesp, Netherlands

[2] Wageningen Univ, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands

[3] Univ Utrecht, NL-3584 CH Utrecht, Netherlands

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 26期

关键词：

D O I：

10.1016/j.tetlet.2008.04.129

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Ruphos-mediated Suzuki cross-coupling between (hetero)aryl bromides and secondary alkyltrifluoroborates is described using palladium catalysis. The Ruphos ligand showed superior properties as compared to S-Phos in this type of reaction. This method constitutes a valuable extension to current methods for the straightforward production of secondary-alkylated (hetero)aryl derivatives. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：4122 / 4124

页数：3

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