Highly regloselective arylation of Sp3 C-H bonds catalyzed by palladium acetate

被引：1303

作者：

Zaitsev, VG ^{[1
]}

Shabashov, D ^{[1
]}

Daugulis, O ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 38期

关键词：

D O I：

10.1021/ja054549f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new palladium-catalyzed arylation process based on C-H activation has been developed. The utilization of pyridine-containing directing groups allows the β-arylation of carboxylic acid derivatives and γ-arylation of amine derivatives. Both primary and secondary sp3 C-H bonds, as well as sp2 C-H bonds, are reactive. Copyright © 2005 American Chemical Society.

引用

页码：13154 / 13155

页数：2

共 34 条

[31] ORTHO-ALKYLATION OF ACETANILIDES USING ALKYL-HALIDES AND PALLADIUM ACETATE [J].